Thiophene-substituted fulleropyrrolidine derivatives as acceptor molecules in a thin film organic solar cell

被引：34

作者：

Yoshimura, Ken ^{[1
,2
]}

Matsumoto, Kei ^{[1
]}

Uetani, Yasunori ^{[2
]}

Sakumichi, Shigeki ^{[1
]}

Hayase, Shuichi ^{[1
]}

Kawatsura, Motoi ^{[1
]}

Itoh, Toshiyuki ^{[1
]}

机构：

[1] Tottori Univ, Dept Chem & Biotechnol, Grad Sch Engn, Tottori 6808552, Japan

[2] Sumitomo Chem Co Ltd, Tsukuba, Ibaraki 3003294, Japan

来源：

TETRAHEDRON | 2012年 / 68卷 / 18期

关键词：

PHOTOINDUCED ELECTRON-TRANSFER; FULLERENE DERIVATIVES; OLIGOTHIOPHENE DERIVATIVES; PHOTOVOLTAIC CELLS; CHARGE SEPARATION; POLYMER; SOLUBILITY; RECOMBINATION; EFFICIENT; SOLVENTS;

D O I：

10.1016/j.tet.2012.02.080

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A study of the design of thiophene-substituted fulleropyrrolidine derivatives as the acceptor in photovoltaic cells has been carried out using poly(3-hexylthiophene) (P3HT) as the model donor polymer. It was found that five types of thiophene-substituted fulleropyrrolidine worked as a good acceptor partner with P3HT, and the highest power conversion efficiency (PCE) was obtained for 1-(2-(2-methoxyethoxy) ethyl)-2-(2-thiophen-2-yl)fulleropyrrolidine (2.99%); this is superior to that of the P3HT polymer including methyl [C60]-PCBM under the same experimental conditions. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：3605 / 3610

页数：6

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