Photoisomerization of sultams derived from saccharin;: Part 3:: Dihydro[1]benzothieno[3,2-b]pyrrole 4,4-dioxides from dihydropyrrolo[1,2-b][1,2]benzisothiazole 5,5-dioxides

被引:0
|
作者
Elghamry, I
Döpp, D [1 ]
Henkel, G
机构
[1] Gerhard Mercator Univ Duisburg, Div Organ Chem, D-47048 Duisburg, Germany
[2] Gerhard Mercator Univ Duisburg, Div Solid State Chem, D-47048 Duisburg, Germany
来源
SYNTHESIS-STUTTGART | 2001年 / 08期
关键词
photoisomerization; sultams; dihydro[1]benzothieno[3,2-b]pyrrole 4,4-dioxides;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
1-Substituted 2,3-dihydropyrrolo[1,2-b][1,2]benzisothiazole 5,5-dioxides 7a-c,e undergo a smooth and efficient transformation into the 2,3-dihydro[1]benzothieno[3,2-b]pyrrole 4,4-dioxides 8a-c,e upon irradiation at 254 nm in acetonitrile. The structures of the products have been elucidated by spectroscopic methods and a single crystal X-ray structure determination for 8b.
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页码:1223 / 1227
页数:5
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