Composition and thermodynamic properties of thermal plasma with condensed phases

被引:33
|
作者
Coufal, O. [1 ]
Zivny, O. [2 ]
机构
[1] Brno Univ Technol, Fac Elect Engn & Commun, Brno 61600, Czech Republic
[2] Brno Univ Technol, Fac Chem, Brno 61200, Czech Republic
来源
EUROPEAN PHYSICAL JOURNAL D | 2011年 / 61卷 / 01期
关键词
EQUILIBRIUM COMPOSITION; CHEMICAL-EQUILIBRIUM; PARTITION-FUNCTIONS;
D O I
10.1140/epjd/e2010-10211-3
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The initial relations of a method for calculating the composition and thermodynamic properties of a closed heterogeneous system in thermodynamic equilibrium at constant pressure and temperature are given. The gaseous phase is always present in the system, and substances in the condensed state can also be present, which are divided into several condensed phases. The essence of the method consists in the minimizing the Gibbs energy of a system in ideal state. The application possibilities of the method described are discussed in detail. The main aim of the article is to provide solutions to problems arising in the calculations of composition and thermodynamic properties. These problems are not only of physico-chemical nature but they also relate to the numerical calculations and stability. The nature of the problems is general and independent of computation method.
引用
收藏
页码:131 / 151
页数:21
相关论文
共 50 条
  • [1] Composition and thermodynamic properties of thermal plasma with condensed phases
    O. Coufal
    O. Živný
    The European Physical Journal D, 2011, 61 : 131 - 151
  • [2] The thermodynamic properties of chlorine condensed phases
    Arblaster, J. W.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2013, 56 : 12 - 14
  • [3] Composition and thermodynamic properties of thermal plasma up to 50 kK
    Coufal, O.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (11) : 3371 - 3385
  • [4] Thermodynamic description of condensed phases
    Wunderlich, Bernhard
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2010, 102 (02) : 413 - 424
  • [5] Thermodynamic description of condensed phases
    Bernhard Wunderlich
    Journal of Thermal Analysis and Calorimetry, 2010, 102 : 413 - 424
  • [6] A re-assessment of the thermodynamic properties of iodine condensed phases
    Arblaster, J. W.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2011, 43 (11): : 1579 - 1582
  • [7] APPLICATION OF MODELS FOR ANALYSIS AND EVALUATION OF THERMODYNAMIC PROPERTIES OF CONDENSED PHASES
    ANSARA, I
    BONNIER, E
    MATHIEU, JC
    ZEITSCHRIFT FUR METALLKUNDE, 1973, 64 (04): : 258 - 268
  • [8] Improvements in the assessment of the thermodynamic properties of condensed and gaseous phases of the CsOH compound
    Roki, Fatima-Zhara
    Ohnet, Marie-Noelle
    Fillet, Sylvie
    Chatillon, Christian
    Nuta, Ioana
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2015, 80 : 147 - 160
  • [9] Calculation of 2-temperature plasma thermo-physical properties considering condensed phases: application to CO2-CH4 plasma: part 1. Composition and thermodynamic properties
    Wu, Yi
    Chen, Zhexin
    Rong, Mingzhe
    Cressault, Yann
    Yang, Fei
    Niu, Chunping
    Sun, Hao
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2016, 49 (40)
  • [10] Thermodynamic properties of dibenzo-p-dioxin, dibenzofuran, and their polychlorinated derivatives in the gaseous and condensed phases.: 2.: Thermodynamic properties of condensed compounds
    Iorish, VS
    Dorofeeva, OV
    Moiseeva, NF
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (02): : 286 - 298