A Critical Assessment of Li/MgO-Based Catalysts for the Oxidative Coupling of Methane

被引：212

作者：

Arndt, Sebastian ^{[1
]}

Laugel, Guillaume ^{[1
]}

Levchenko, Sergey ^{[2
]}

Horn, Raimund ^{[3
]}

Baerns, Manfred ^{[3
]}

Scheffler, Matthias ^{[2
]}

Schloegl, Robert ^{[3
]}

Schomaecker, Reinhard ^{[1
]}

机构：

[1] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany

[2] Max Planck Gesell, Fritz Haber Inst, Theory Dept, Berlin, Germany

[3] Max Planck Gesell, Fritz Haber Inst, Dept Inorgan Chem, Berlin, Germany

来源：

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2011年 / 53卷 / 04期

关键词：

Li/MgO; Oxidative coupling of methane; Oxidative dehydrogenation of ethane; OCM; ODH; MAGNESIUM-OXIDE CATALYSTS; LI-DOPED MGO; TRAPPED-HOLE CENTERS; BLANK REACTOR CORRECTIONS; GAS-PHASE; PROMOTED MGO; SURFACE-AREA; ALKALINE-EARTH; ACTIVE-SITE; HYDROGEN ABSTRACTION;

D O I：

10.1080/01614940.2011.613330

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Li/MgO is one of the most frequently investigated catalysts for the oxidative coupling of methane. Besides catalytic testing, it is also a suitable system to perform surface science experiments and quantum chemical calculations, which is not possible for many other active catalysts. However, the real structure of Li/MgO, the nature of the active center and the structure - activity relationship remain unclear, despite all the research that has been done. The aim of this review is to summarize the available knowledge on Li/MgO to structure and accelerate and improve the ongoing work on this catalytic system.

引用

页码：424 / 514

页数：91

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