Synthesis and reactivity study of gadolinia doped ceria-nickel: A potential anode material for solid oxide fuel cell

被引:13
|
作者
Datta, Pradyot [1 ,2 ]
Majewski, Peter [3 ]
Aldinger, Fritz [1 ,2 ]
机构
[1] Univ Stuttgart, Max Planck Inst Met Forsch, Pulvermet Laboratorium, D-70569 Stuttgart, Germany
[2] Univ Stuttgart, Inst Nichtmet & Anorgan Mat, Pulvermet Laboratorium, D-70569 Stuttgart, Germany
[3] Univ S Australia, Ian Wark Res Inst, Mawson Lakes, SA 5095, Australia
关键词
oxide materials; sintering; thermal expansion; photoelectron spectroscopies; X-ray diffraction;
D O I
10.1016/j.jallcom.2007.01.143
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of Ce0.9Gd0.1O2-delta-Ni cermets with different Ni contents were prepared by conventional sintering process. The chemical compatibility between Ce0.9Gd0.1O2-delta (CGO) and Ni was investigated by X-ray diffraction, scanning electron microscopy, differential scanning calorimetry and X-ray photoelectron spectroscopy. Sintering and reduction temperatures of CGO-Ni cermets were also identified. Thermal expansion coefficients of the cermets were measured as a function of Ni content. No reaction or solid solubility between CGO and Ni was found. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:454 / 460
页数:7
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