Terbium(III) complexes with pyrazolones-5 on zirconium phosphate: Synthesis and luminescent properties

被引：3
|
作者：
Meshkova, SB [1 ]
Topilova, ZM [1 ]
Litvinenko, AV [1 ]
Nazarenko, NA [1 ]
机构：
[1] Ukrainian Acad Sci, Bagatskii Physicochem Inst, Odessa, Ukraine
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 10期
关键词：
Phosphate; Physical Chemistry; Zirconium; Reaction Site; Luminescent Property;
D O I：
10.1023/A:1026032402172
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Sorption of Tb3+, ions by zirconium phosphate (ZrP), their complexation with some pyrazolones-5, and composition of compounds formed on a solid matrix are studied. Unlike solutions with the ratio Tb : pyrazolone = 1 : 3. compounds formed on ZrP have the ratio Tb : L = 1 : 3, 1 : 2, and 1 : 1, depending on the availability and size of a substituent at the reaction site. The luminescence intensity of the adsorbed Tb pyrazolonates as found to correlate with a sum of the Hammer induction sigma-constants of substituents in the ligand molecule. The luminescence intensity of the studied complexes on ZrP is two times and more hi.-her than that in solutions, which makes it possible to use ZrP as a solid substrate.
引用
收藏
页码：732 / 736
页数：5
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