Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m-Terphenyl Isocyanides

被引：21

作者：

Agnew, Douglas W. ^{[1
]}

Gembicky, Milan ^{[1
]}

Moore, Curtis E. ^{[1
]}

Rheingold, Arnold L. ^{[1
]}

Figueroa, Joshua S. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, 9500 Gilman Dr,Mail Code 0358, La Jolla, CA 92093 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 46期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; COMPLEXES; TRANSITION; REACTIVITY;

D O I：

10.1021/jacs.6b10460

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of 3D and 2D Cu(I) coordination networks using ditopic m-terphenyl isocyanides is described. The incorporation of sterically encumbering substituents enables the controlled, solid-state preparation of Cu(I) tris-isocyanide nodes with a labile solvent ligand in a manner mirroring solution-phase chemistry of monomeric complexes. The protection afforded by the m-terphenyl groups is also shown to engender significant stability towards heat as well as acidic or basic conditions, resulting in robust single-metal-node networks that can transition from 3D to 2D extended structures.

引用

页码：15138 / 15141

页数：4