Manganese-catalyzed regiospecific sp3 C-S bond formation through C-C bond cleavage of cyclobutanols

被引：60
|
作者：
Ren, Rongguo [1 ]
Wu, Zhen [1 ]
Zhu, Chen [1 ,2 ]
机构：
[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, 199 Ren Ai Rd, Suzhou 215123, Jiangsu, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 52期
基金：
中国国家自然科学基金;
关键词：
OXIDATIVE RING-CLEAVAGE; TERT-CYCLOBUTANOLS; H FLUORINATION; ASYMMETRIC ARYLATION; VINYL AZIDES; CYCLOPROPANOLS; ACTIVATION; STRATEGY; KETONES; PORPHYRIN;
D O I：
10.1039/c6cc01843b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A manganese-catalyzed regioselective sp(3) C-S bond formation through C-C bond cleavage of cyclobutanols is described. A variety of primary and secondary alkyl thioethers are efficiently prepared under mild reaction conditions. The mechanistic pathways involving radical-mediated tandem C-C bond cleavage and C-S bond formation are proposed.
引用
收藏
页码：8160 / 8163
页数：4
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