Three-dimensional structure of nanocomposites from atomic pair distribution function analysis:: Study of polyaniline and (polyaniline)0.5V2O5•1.0H2O

被引:50
|
作者
Petkov, V [1 ]
Parvanov, V
Trikalitis, P
Malliakas, C
Vogt, T
Kanatzidis, MG
机构
[1] Cent Michigan Univ, Dept Phys, Mt Pleasant, MI 48859 USA
[2] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA
[3] Brookhaven Natl Lab, Dept Phys, Upton, NY 11973 USA
关键词
D O I
10.1021/ja051315n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The three-dimensional structures of emeraldine base polyaniline (PANI) and (polyaniline)(0.5)V(2)O(5.)1.0H(2)O have been determined by total X-ray scattering experiments. Atomic pair distribution functions (PDF) were measured to obtain experimental observables against which structural models were tested and refined. The PDF approach is necessary because of the limited structural coherence in these nanostructured materials. Polyaniline possesses a well-defined local atomic arrangement that can be described in terms of an 84-atom orthorhombic unit cell. The nanocomposite (PANI)(0.5)V2O5 center dot 1.0H(2)O too is locally well ordered and may be described in terms of a small number of structure-sensible parameters. The PDF approach allows the construction of structure models of PANI and (PANI)(0.5)V2O5 center dot 1.0H(2)O on the basis of which important materials' properties can be explained predicted and possibly improved.
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页码:8805 / 8812
页数:8
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