Sol-Gel route to barium aluminosilicate (BAS) glass-ceramics

A new idea was proposed for solving the problems caused by different hydrolysis rate of alkoxides in Sol-Gel processes. The new idea is that the highest-hydrolysis-rate alkoxide is supposed to be hydrolysized slowly and homogeneously at first under a controllable condition: and meanwhile, its hydrolysis intermediates polymerize with lower-hydrolysis-rate alkoxides. Based on this new idea, a Sol-Gel process with lower cost and a simple procedure was developed for synthesizing BAS glass;ceramics. XRD, DTA and Laser Raman Spectrum were used to det;ect the molecular structures and crystallization behaviors of a gel and a gel-derived glass. The as-prepared gelis amorphous with (Si, AI)-O network structures. The temperature of maximum-nucleation-rate of the amorphous is about 938 degrees C, and the temperature of maximum-crystal-growth is about 1164 degrees C.