Spectroscopic Study of the Semihydrate of the Dodecahydro-closo-dodecaborate of 2,4,6-Triamino-1,3,5-triazine

被引：1
|
作者：
Saldin, V. I. [1 ]
Slobodyuk, A. B. [1 ]
Savchenko, N. N. [1 ]
Ignat'eva, L. N. [1 ]
Buznik, V. M. [1 ]
机构：
[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2018年 / 92卷 / 11期
关键词：
IR; NMR B-11; H-1; C; N; semihydrate of 2,4,6-triamino-1,3,5-triazine (melamine) dodecahydro-closo-dodecaborate; directed localized cation-anion interactions; Hartree-Fock method; FEATURES; MELAMINE; SALTS;
D O I：
10.1134/S0036024418110353
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The presence of directed localized cation-anion interactions in the semihydrate of 2,4,6-triamino-1,3,5-triazine (melamine) dodecahydro-closo-dodecaborate (C3H6N6H)(2)B12H12 <bold> </bold>0.5H(2)O is discovered by means of IR and NMR-spectroscopy (B-11, H-1, C, N). The hypothesis that melamine protonation proceeds on the ring atom of nitrogen is confirmed via quantum-chemical calculations.
引用
收藏
页码：2210 / 2214
页数：5
相关论文
共 50 条
  • [1] Spectroscopic Study of the Semihydrate of the Dodecahydro-closo-dodecaborate of 2,4,6-Triamino-1,3,5-triazine
    V. I. Saldin
    A. B. Slobodyuk
    N. N. Savchenko
    L. N. Ignat’eva
    V. M. Buznik
    Russian Journal of Physical Chemistry A, 2018, 92 : 2210 - 2214
  • [2] PREPARATION AND PROPERTIES OF A POLYSTYRENE EXCHANGER WITH 2,4,6-TRIAMINO-1,3,5-TRIAZINE AS ANCHOR GROUP
    LIESER, KH
    THYBUSCH, D
    FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1981, 306 (2-3): : 100 - 105
  • [3] Dielectric and Impedance Spectroscopic Investigation of (3-Nitrophenol)-2,4,6-Triamino-1,3,5-Triazine: An Organic Crystalline Material
    Kanagathara, N.
    Sankar, S.
    Saravanan, L.
    Natarajan, V.
    Elangovan, S.
    ADVANCES IN CONDENSED MATTER PHYSICS, 2022, 2022
  • [4] Interaction between 2,4,6-triamino-1,3,5-triazine and alkyl esters of phosphonic and phosphorus acids
    Troev, K
    Tsevi, R
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1998, 133 : 61 - 68
  • [5] Thermal Decomposition Behaviour of Bis(4-Nitrophenol)-2,4,6-Triamino-1,3,5-Triazine Monohydrate
    Kanagathara, N.
    Marchewka, M. K.
    Anbalagan, G.
    ACTA PHYSICA POLONICA A, 2016, 129 (06) : 1235 - 1241
  • [6] X-RAY AND NEUTRON CRYSTAL-STRUCTURE OF 2,4,6-TRIAMINO-1,3,5-TRIAZINE (MELAMINE)
    VARGHESE, JN
    OCONNELL, AM
    MASLEN, EN
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (JUL15): : 2102 - 2108
  • [7] 2,4,6-triamino-1,3,5-triazine-1,3-diium aquapentafluoridoaluminate
    Cadiau, A.
    Hemon-Ribaud, A.
    Leblanc, M.
    Maisonneuve, V.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M523 - U140
  • [8] DETERMINATION OF TRACE 2,4,6-TRIAMINO-1,3,5-TRIAZINE IN WATER USING THE ACTIVATED CARBON ADSORPTION METHOD AND GC/MS
    KADOKAMI, K
    SHINOHARA, R
    BUNSEKI KAGAKU, 1986, 35 (10) : 875 - 879
  • [9] SULFUR-DIOXIDE ADSORPTION FROM EXHAUST-GASES BY ADSORBENTS BASED ON 2,4,6-TRIAMINO-1,3,5-TRIAZINE
    POSTNIKOVA, IN
    PAVLOVA, IV
    KOGTEV, SE
    KSANDROV, NV
    NIKANDROV, IS
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1994, 67 (11) : 1669 - 1670
  • [10] 4-Nitrophenol-2,4,6-triamino-1,3,5triazine-water (2/1/1)
    Kanagathara, N.
    Chakkaravarthi, G.
    Marchewka, M. K.
    Gunasekaran, S.
    Anbalagan, G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2286 - +
12345