Structural Characterization of a Copper Nitrosyl Complex with a {CuNO}10 Configuration

被引：59
|
作者：
Wright, Ashley M. [1 ]
Wu, Guang [1 ]
Hayton, Trevor W. [1 ]
机构：
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 41期
关键词：
NITRITE REDUCTASE; SPECTROSCOPIC CHARACTERIZATION; OXIDE; COORDINATION; FLUORIDE; DENITRIFICATION; MECHANISM; MODELS; LIGAND; CATION;
D O I：
10.1021/ja105930b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of a {CuNO}(10) complex, namely, [Cu(CH3NO2)(5)(NO)][PF6](2), has been achieved by the addition of [NO][PF6] to copper metal powder in the presence of nitromethane. In the solid state, this complex exhibits a bent Cu-N-O moiety [Cu-N-O = 121.0(3)degrees] and a long Cu-N bond. This complex readily reacts with mesitylene to form [mesitylene, NO][PF6] and [Cu(eta(2)-1,3,5-Me3C6H3)(2)][PF6] by transfer of NO+ to the mesitylene ring.
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页码：14336 / 14337
页数：2
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