Preparation of KOH-doped PVA/PSSA Solid Polymer Electrolyte for DMFC: The Influence of TiO2 and PVP on Performance of Membranes

被引:15
|
作者
de Oliveira, A. H. P. [1 ,2 ]
Nascimento, M. L. F. [2 ]
de Oliveira, H. P. [1 ]
机构
[1] Univ Fed Vale Sao Francisco, Inst Pesquisa Ciencia Mat, BR-48902300 Juazeiro, BA, Brazil
[2] Univ Fed Bahia, Escola Politecn, Dept Engn Quim, BR-40210630 Salvador, BA, Brazil
关键词
Alkaline Fuel Cell; Conductivity; Direct Methanol Fuel Cell; Methanol Fuel Cells; Polymer Electrolyte Membrane; LINKED POLY(VINYL ALCOHOL); PROTON-EXCHANGE MEMBRANES; CO-MALEIC ACID); FUEL-CELLS; CONDUCTING MEMBRANES; POLYVINYL-ALCOHOL; ALKALINE DMFC; SULFONIC-ACID);
D O I
10.1002/fuce.201500199
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The development of low cost alkaline anion solid exchange membranes requires high ionic conductivity, low liquid uptake, strong mechanical properties and chemical stability. PVA/PSSA blends cross-linked with glutaraldehyde and decorated with titanium dioxide nanoparticles introduce advantages relative to the pristine membrane of PVA and PVA/PVP membranes due to their improved electrical response and low methanol uptake/swelling ratio allowing their use in alkaline direct methanol fuel cells.
引用
收藏
页码:151 / 156
页数:6
相关论文
共 50 条
  • [1] Electrical conductivity studies on PVA/PVP-KOH alkaline solid polymer blend electrolyte
    Hatta, FF
    Yahya, MZA
    Ali, AMM
    Subban, RHY
    Harun, MK
    Mohamad, AA
    IONICS, 2005, 11 (5-6) : 418 - 422
  • [2] Electrical conductivity studies on PVA/PVP-KOH alkaline solid polymer blend electrolyte
    F. F. Hatta
    M. Z. A. Yahya
    A. M. M. Ali
    R. H. Y. Subban
    M. K. Harun
    A. A. Mohamad
    Ionics, 2005, 11 : 418 - 422
  • [3] PLASTICIZED PVA/PVP-KOH ALKALINE SOLID POLYMER BLEND ELECTROLYTE FOR ELECTROCHEMICAL CELLS
    Hatta, F. F.
    Kudin, T. I. T.
    Subban, R. H. Y.
    Ali, A. M. M.
    Harun, M. K.
    Yahya, M. Z. A.
    FUNCTIONAL MATERIALS LETTERS, 2009, 2 (03) : 121 - 125
  • [4] Obtaining Electrospun Membranes of Chitosan/PVA and TiO2 as a Solid Polymer Electrolyte with Potential Application in Ion Exchange Membranes
    Gomez, Elio Enrique Ruiz
    Hernandez, Jose Herminsul Mina
    MEMBRANES, 2023, 13 (11)
  • [5] Enhancement of electrochemical performance in supercapacitors using TiO2 nanoparticles-doped PVA-KOH gel electrolyte
    Wongsaprom, Kwanruthai
    Insee, Pornchita
    Boonraksa, Nattarika
    Swatsitang, Ekaphan
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2025, 978
  • [6] Preparation of alkaline solid polymer electrolyte based on PVA-TiO2-KOH-H2O and its performance in Zn-Ni battery
    Wu, Qiumei
    Zhang, Jifu
    Sang, Shangbin
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (11) : 2691 - 2695
  • [7] UV ABSORPTION PROPERTIES OF DOPED PVA TiO2 MEMBRANES
    Todica, Mihai
    Udrescu, Luciana
    Pop, Cornel Viorel
    Pop, Mihaela
    Traian, Stefan
    Simon, Simion
    STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA, 2011, 56 (03): : 165 - 169
  • [8] Alkaline solid polymer electrolyte membranes based on structurally modified PVA/PVP with improved alkali stability
    Qiao, Jinli
    Fu, Jing
    Lin, Rui
    Ma, Jianxin
    Liu, Jianshe
    POLYMER, 2010, 51 (21) : 4850 - 4859
  • [9] TiO2 nanoparticles prepared by mechanical reduction technique for superior DMFC nanocomposite PVA membranes
    Gohel, Jignasa Vimal
    Mishra, Preeti Sheshmani
    Murthy, Z. V. P.
    SEPARATION SCIENCE AND TECHNOLOGY, 2019, 54 (02) : 233 - 246
  • [10] AC and DC electrical transport properties of potassium permanganate doped PVA-PVP solid polymer electrolyte
    Veena, G.
    Lobo, Blaise
    MATERIALS RESEARCH EXPRESS, 2019, 6 (03)