Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2

被引：54
|
作者：
Nishihara, Y [1 ]
Onodera, H [1 ]
Osakada, K [1 ]
机构：
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 02期
关键词：
D O I：
10.1039/b308741g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C6F5)I(PR3)(2)(PR3 = PEt3, PMe2Ph, PMePh2) in the presence of Ag2O afforded transPd(C6F5)(2,4,6-C6F3H2)(PR3)(2) which are stabilized by fluorine atoms in the ortho positions.
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页码：192 / 193
页数：2
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