Iron-catalyzed Sonogashira reactions

被引：217
|
作者：
Carril, Monica [1 ]
Correa, Arkaitz [1 ]
Bolm, Carsten [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 26期
关键词：
arylation; C-C coupling; homogeneous catalysis; iron; synthetic methods;
D O I：
10.1002/anie.200801539
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) With an iron will: Terminal alkynes undergo reaction with aryl and heteroaryl iodides in the presence of an iron catalyst formed from FeCl3 and N,N′-dimethylethylenediamine (dmeda, see scheme). The method displays a broad substrate scope and is economical, environmentally friendly, and experimentally simple. A "one-pot" Sonogashira/intramolecular hydroalkoxylation has also been achieved by this method. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4862 / 4865
页数：4
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