Sol-gel reaction of porphyrin-based superstructures in the organogel phase: Creation of mechanically reinforced porphyrin hybrids

被引：77

作者：

Kishida, T ^{[1
]}

Fujita, N ^{[1
]}

Sada, K ^{[1
]}

Shinkai, S ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 20期

关键词：

D O I：

10.1021/ja050563g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have demonstrated that a one-dimensional molecular assembly created by an H-aggregated porphyrin·Cu(II) stack can be immobilized, without a morphological change, by sol-gel polycondensation of the peripheral triethoxysilyl groups. The resultant gel prepared according to this flowchart has gained a very high thermal stability as well as a unique mechanical strength. Copyright © 2005 American Chemical Society.

引用

页码：7298 / 7299

页数：2

共 16 条

[1] Sol-gel reaction of porphyrin-based superstructures in the organogel phase: Creation of mechanically reinforced porphyrin hybrids
1600, American Chemical Society, Columbus, United States (127):
[2] Porphyrin gels reinforced by sol-gel reaction via the organogel phase
Kishida, T
Fujita, N
Sada, K
Shinkai, S
LANGMUIR, 2005, 21 (21) : 9432 - 9439
[3] Immobilization of a two-dimensional porphyrin assembly by sol-gel polycondensation in the gel phase
Kishida, T
Fujita, N
Sada, K
Shinkai, S
CHEMISTRY LETTERS, 2004, 33 (08) : 1002 - 1003
[4] Diffuse reflectance spectroscopy under a reactive gas: Reaction of NO with a ferri porphyrin sol-gel material.
DeLeo, MA
VanWuellen, L
Ford, PC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 139 - INOR
[5] Sol-gel phase transition of brucine-appended porphyrin gelator:: a study by vibrational circular dichroism spectroscopy
Setnicka, V
Urbanová, M
Pataridis, S
Král, V
Volka, K
TETRAHEDRON-ASYMMETRY, 2002, 13 (24) : 2661 - 2666
[6] Organic-inorganic Polymer Nano-hybrids Based on Sol-gel Reaction
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复旦学报(自然科学版), 2007, (05) : 556 - 556
[7] Porphyrin-Based Covalent Organic Framework Reinforced Hollow Fiber for Solid-Phase Microextraction of Tebuconazole and Propiconazole
Kavian, Marzieh
Ghani, Milad
Raoof, Jahan Bakhsh
JOURNAL OF SEPARATION SCIENCE, 2025, 48 (01)
[8] Sol-gel polycondensation in a cyclohexane-based organogel system in helical silica: Creation of both right- and left-handed silica structures by helical organogel fibers
Jung, JH
Ono, Y
Shinkai, S
CHEMISTRY-A EUROPEAN JOURNAL, 2000, 6 (24) : 4552 - 4557
[9] Sol-gel polycondensation of tetraethyl orthosilicate (TEOS) in sugar-based porphyrin organogels: Inorganic conversion of a sugar-directed porphyrinic fiber library through sol-gel transcription processes
Kawano, S
Tamaru, S
Fujita, N
Shinkai, S
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (02) : 343 - 351
[10] Sol-gel polycondensation in a cyclohexane-based organogel system in helical silica: Creation of both right- and left-handed silica structures by helical organogel fibers
2000, Wiley-VCH Verlag (06)

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