Hybrid α-Fe2O3@Ni(OH)2 nanosheet composite for high-rate-performance supercapacitor electrode

被引:29
|
作者
Jiang, Hong [1 ]
Ma, Haifeng [2 ]
Jin, Ying [2 ,3 ]
Wang, Lanfang [2 ]
Gao, Feng [1 ]
Lu, Qingyi [2 ]
机构
[1] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Dept Mat Sci & Engn, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Sch Chem & Chem Engn,State Key Lab Coordinat Chem, Inst Coordinat Chem,Nanjing Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[3] Anhui Polytech Univ, Coll Biol & Chem Engn, Wuhu 241000, Anhui, Peoples R China
来源
SCIENTIFIC REPORTS | 2016年 / 6卷
基金
中国国家自然科学基金;
关键词
THIN-FILM; OXIDE; ARRAYS; FOAM;
D O I
10.1038/srep31751
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In this study, we report a facile fabrication of ultrathin two-dimensional (2D) nanosheet hybrid composite, alpha-Fe2O3 nanosheet@Ni(OH)(2) nanosheet, by a two-step hydrothermal method to achieve high specific capacitance and good stability performance at high charging/discharging rates when serving as electrode material of supercapacitors. The alpha-Fe2O3@Ni(OH)(2) hybrid electrode not only has a smooth decrease of the specific capacitance with increasing current density, compared with the sharp decline of single component of Ni(OH)(2) electrode, but also presents excellent rate capability with a specific capacitance of 356 F/g at a current density of 16 A/g and excellent cycling stability (a capacity retention of 93.3% after 500 cycles), which are superior to the performances of Ni(OH)(2) with a lower specific capacitance of 132 F/g and a lower capacity retention of 81.8% at 16 A/g. The results indicate such hybrid structure would be promising as excellent electrode material for good performances at high current densities in the future.
引用
收藏
页数:7
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