Micellization of polyblock copolymers in a selective solvent

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作者
Dubrovina, LV
Bragina, TP
Makarova, LI
Filimonova, LV
Pavlova, SSA
Zhdanov, AA
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The association of polyblock copolymer, poly(siloxane-co-carbonate-co-urethane), in benzene (selective solvent for siloxane component) was studied by light scattering, viscometry, and sedimentation methods. Anomalous micellization was observed in a solution in the concentration range of 0.02-1.4 g/dl: as the concentration increases, the associates pass through the region of metastable microphase separation and then form polymolecular micelles.
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页码:1419 / 1422
页数:4
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