Reversible Photoalignment of Azobenzene in the SURMOF HKUST-1

被引：8

作者：

Koehler, Tillmann ^{[1
]}

Strauss, Ina ^{[2
]}

Mundstock, Alexander ^{[2
]}

Caro, Juergen ^{[2
]}

Marlow, Frank ^{[1
,3
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

[2] Leibniz Univ Hannover, D-30167 Hannover, Germany

[3] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen CENIDE, D-47057 Duisburg, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2021年 / 12卷 / 36期

关键词：

METAL-ORGANIC FRAMEWORKS; OPTICAL-PROPERTIES; FILMS; PHOTOISOMERIZATION; NANOCOMPOSITES; ISOMERIZATION; REORIENTATION; CU-3(BTC)(2); MECHANISM; POLYMERS;

D O I：

10.1021/acs.jpclett.1c02489

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Azobenzene guest molecules in the metal-organic framework structure HKUST-1 show reversible photochemical switching and, in addition, alignment phenomena. Since the host system is isotropic, the orientation of the guest molecules is induced via photo processes by polarized light. The optical properties of the thin films, analyzed by interferometry and UV/vis spectroscopy, reveal the potential of this alignment phenomenon for stable information storage.

引用

页码：8903 / 8908

页数：6

共 50 条

[1] Improved catalytic hydrogen release of quasi HKUST-1 compared to HKUST-1
Bagheri, Minoo
Melillo, Arianna
Ferrer, Belen
Masoomi, Mohammad Yaser
Garcia, Hermenegildo
CHEMICAL COMMUNICATIONS, 2021, 57 (90) : 11964 - 11967
[2] Research progress in structural regulation and applications of HKUST-1 and HKUST-1 based materials
Zhao, Tian
Nie, Saiqun
Luo, Mingliang
Xiao, Pengcheng
Zou, Minmin
Chen, Yi
JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 974
[3] Adsorption of insulin by HKUST-1
Marshall, Andrew
Mensinger, Zachary
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[4] Enhancing the Quality of MOF Thin Films for Device Integration Through Machine Learning: A Case Study on HKUST-1 SURMOF Optimization
Pilz, Lena
Koenig, Meike
Schwotzer, Matthias
Gliemann, Hartmut
Woell, Christof
Tsotsalas, Manuel
ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (44)
[5] On the HKUST-1/GO and HKUST-1/rGO Composites: The Impact of Synthesis Method on Physicochemical Properties
Jagodka, Paulina
Matus, Krzysztof
Lamacz, Agata
MOLECULES, 2022, 27 (20):
[6] Photoswitchable nanoporous films by loading azobenzene in metal-organic frameworks of type HKUST-1
Mueller, Kai
Wadhwa, Jasmine
Malhi, Jasleen Singh
Schoettner, Ludger
Welle, Alexander
Schwartz, Heidi
Hermann, Daniela
Ruschewitz, Uwe
Heinke, Lars
CHEMICAL COMMUNICATIONS, 2017, 53 (57) : 8070 - 8073
[7] Functionalization effects on HKUST-1 and HKUST-1/graphene oxide hybrid adsorbents for hydrogen sulfide removal
Bhoria, Nidhika
Basina, Georgia
Pokhrel, Jeewan
Reddy, K. Suresh Kumar
Anastasiou, Stavroula
Balasubramanian, Vaithilingam V.
AlWahedi, Yasser Fowad
Karanikolos, Georgios N.
JOURNAL OF HAZARDOUS MATERIALS, 2020, 394
[8] The Dielectric Behavior of Protected HKUST-1
Sorbara, Simona
Casati, Nicola
Colombo, Valentina
Bossola, Filippo
Macchi, Piero
CHEMISTRY-SWITZERLAND, 2022, 4 (02): : 576 - 591
[9] HKUST-1 growth on glassy carbon
Balakrishnan, Sivakumar
Downard, Alison J.
Telfer, Shane G.
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (48) : 19207 - 19209
[10] A unique photoswitch: intrinsic photothermal heating induced reversible proton conductivity of a HKUST-1 membrane
Wang, Shilin
Li, Peipei
Fan, Shuaikang
Fang, Zhou
Wang, Xiaobin
Li, Zhuoyi
Peng, Xinsheng
DALTON TRANSACTIONS, 2021, 50 (08) : 2731 - 2735

← 1 2 3 4 5 →