A benzothiazole-based chemosensor for significant fluorescent turn-on and ratiometric detection of Al3+ and its application in cell imaging

被引：63
|
作者：
Zeng, Shuang [1 ]
Li, Shi-Jie [2 ]
Sun, Xue-Jiao [1 ]
Li, Ming-Qiang [1 ]
Xing, Zhi-Yong [1 ]
Li, Jin-Long [3 ]
机构：
[1] Northeast Agr Univ, Coll Sci, Dept Appl Chem, Harbin 150030, Heilongjiang, Peoples R China
[2] Northeast Agr Univ, Coll Life Sci, Harbin 150030, Heilongjiang, Peoples R China
[3] Qiqihar Univ, Sch Chem & Chem Engn, Qiqihar 161006, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2019年 / 486卷
关键词：
Benzothiazole; Al3+; Ratiometric detection; Filter paper; Cells HSC; SCHIFF-BASE; ALUMINUM TOXICITY; SECONDARY SENSOR; AQUEOUS-MEDIUM; PROBE; RECOGNITION; DIARYLETHENE; COMPLEX; SWITCH; CU2+;
D O I：
10.1016/j.ica.2018.11.042
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chemosensor Z including benzothiazole fluorophore was synthesized and characterized with NMR and HRMS spectroscopic techniques. Z exhibited fluorescence turn-on and ratiometric absorbance detection of Al3+ ions based on the combination mechanism of CHEF and ESIPT processes. Moreover, the stiochiometry between Z and Al3+ were determined 2:1 through job's plot and HRMS, and the limit of detection was determined as 8.47 nM which was qualified in the detection of Al3+ in drinking water. Especially, Z was achieved in fast identification the existence of Al3+ by filter paper, and cell imaging in human stromal cell (HSC).
引用
收藏
页码：654 / 662
页数：9
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