The Synergistic Effect of BTA-Co System on the Corrosion Inhibition of Mild Steel in 3.5 wt% NaCl Solution

被引:58
|
作者
Akhavan, Hossein [1 ]
Izadi, Mazdak [1 ]
Mohammadi, Iman [1 ]
Shahrabi, Taghi [1 ]
Ramezanzadeh, Bahram [2 ]
机构
[1] Tarbiat Modares Univ, Dept Mat Engn, Fac Engn, Tehran 14115143, Iran
[2] ICST, Dept Surface Coatings & Corros, Tehran 16765654, Iran
关键词
HYDROCHLORIC-ACID SOLUTION; LOW-CARBON STEEL; HETEROCYCLIC-COMPOUNDS; SELECTIVE OXIDATION; RAMAN-SPECTROSCOPY; CHLORIDE SOLUTION; COBALT COMPLEX; COPPER-ALLOYS; BENZOTRIAZOLE; PERFORMANCE;
D O I
10.1149/2.1111810jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this study, the synergistic effect of benzotriazole (BTA) molecules and cobalt cations (Co2+ cations) on the corrosion inhibition of mild steel was studied by electrochemical and surface analysis techniques. The considerable corrosion inhibition efficiency of BTA-Co system was proved by open circuit potential measurements, polarization tests, and electrochemical impedance spectroscopy (EIS) results. Field-emission scanning electron microscopy, energy dispersion spectrometer, X-ray photoelectron spectroscopy, and EIS analysis were employed to characterize the inhibition mechanism of the BTA-Co system. The precipitation of BTA-Co chelate on the steel surface was proposed as the main mechanism for corrosion protection of mild steel in the presence of BTA molecules and Co2+ cations. Also, a mixed-type corrosion inhibition effect of BTA-Co system was shown by polarization tests. (C) 2018 The Electrochemical Society.
引用
收藏
页码:C670 / C680
页数:11
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