Hydrothermal synthesis and structure of a molybdenum oxide (TMA)2[Ni(H2O)6][β-Mo8O26]

被引：4
|
作者：
Lu, SM
Ke, YX
Li, JM [1 ]
Zhang, YG
机构：
[1] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
SOLID STATE SCIENCES | 2003年 / 5卷 / 02期
关键词：
hydrothermal reaction; crystal structure; oxomolybdenum; organic amine;
D O I：
10.1016/S1293-2558(03)00007-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex of (TMA)(2)[Ni(H2O)(6)][beta-Mo8O26] (I) has been synthesized via hydrothermal reaction.under 130 degreesC. The crystal structure was determined by single crystal X-ray diffraction at room temperature. Crystal data: M = 1498.62, Monoclinic, space group C2/c (No. 15), a = 15.9812(13) Angstrom, b = 13.5690(11) Angstrom, c = 16.7782(13) Angstrom, alpha = 90degrees, beta = 96.760(2)degrees, gamma = 90degrees, and Z = 4. It is composed of an inorganic cluster [beta-Mo8O26](4-), six-hydrated bivalent nickel cation, and two organic amines TMA(+). (C) 2003 Editions scientifiques et medicales Elsevier SAS. All rights reserved.
引用
收藏
页码：317 / 320
页数：4
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