Self-template synthesis of biomass-derived 3D hierarchical N-doped porous carbon for simultaneous determination of dihydroxybenzene isomers

Nitrogen doped hierarchical porous carbon materials (HPCs) was achieved by the successful carbonization, using pig lung as biomass precursor. Three-dimensional HPCs constituted with sheets and lines were synergistically inherited from original pig lung. Such structure provided a large specific surface area (958.5 g(-1) m(2)) and rich porous, effectively supported a large number of electroactive species, and greatly enhanced the mass and electron transfer. High graphitization degree of HPCs resulted in good electrical conductivity. Furthermore, the different electronegativity between nitrogen and carbon atoms in HPCs could affect the electron cloud distribution, polarity and then the electrochemical oxidation kinetics of dihydroxybenzene isomers. Based on these characteristics of HPCs, the electrochemical sensor for dihydroxybenzene isomers exhibited high sensitivity, excellent specificity and stability. Quantitative analysis assays by differential pulse voltammetry (DPV) technology showed that the sensor has wide linear ranges (0.5-320, 0.5-340 and 1-360 mu mol L-1) and low detection limits (0.078, 0.057 and 0.371 mu mol L-1) for the catechol, resorcinol and hydroquinone, respectively. This proposed method was successfully applied for simultaneous detection of dihydroxybenzene isomers in river water.