On the origin of the alternating Diels-Alder reactivity in [n]dendralenes

被引：24
|
作者：
Paddon-Row, Michael N. [1 ]
Sherburn, Michael S. [2 ]
机构：
[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia
[2] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 06期
基金：
澳大利亚研究理事会;
关键词：
PRACTICAL SYNTHESIS; DENDRALENE FAMILY; DIMERIZATION; HYDROCARBONS; BUTADIENE; CHEMISTRY; BONDS;
D O I：
10.1039/c1cc15455a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
G4(MP2) calculations on Diels-Alder reactions of [3]- and [4]dendralene have revealed that reactant dendralene conformer populations and closed-shell singlet bis-pericyclic transition states explain their different reactivities.
引用
收藏
页码：832 / 834
页数：3
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