Ionothermal synthesis and characterization of alkali metal polyoxometallates: Structural trends in the (emim)m[An(Mo8O26)] (emim=1-ethyl-3-methylimidazolium; m=2,3; n=1,2; A = K, Rb, Cs) group of compounds

被引：12
|
作者：
Pakhomova, Anna S. [1 ]
Krivovichev, Sergey V. [1 ]
机构：
[1] St Petersburg State Univ, Dept Crystallog, St Petersburg, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 12期
关键词：
Ionothermal synthesis; Alkali metal polyoxometallales; X-ray structure analysis; IONIC LIQUID; ORGANIC FRAMEWORKS; COORDINATION POLYMER; BETA-OCTAMOLYBDATE; CLUSTER; ANION; CRYSTALLIZATION; CATION;
D O I：
10.1016/j.inoche.2010.08.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three novel octamolybdates (emim)(3)K(Mo8O26) (1), (emim)(3)Rb(Mo8O26) (2) and (emim)(2)Cs-2(Mo8O26) (3) (emim = 1-ethyl-3-methylimidazolium) have been prepared by ionothermal reactions using (emim)Br as a solvent. The structures contain octamolybdate anions [beta-Mo8O26](4-). In compounds 1 and 2, [beta-Mo8O26](4-) units are linked by alkali metal cations to form 1D chain structures, while Cs cations in the compound 3 link to polyoxoanions to form a 2D layered structure. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1463 / 1465
页数：3
相关论文
共 50 条
  • [1] Structural trends in the (emim)m[An(Mo8O26)] (emim=1-ethyl-3-methylimidazolium; m=2,3; n=1,2; A=K, Rb, Cs) group of compound
    Pakhomova, Anna
    Krivovichev, Sergey
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2010, 66 : S189 - S189
  • [2] Ionothermal synthesis and characterization of [EMIM]3[(Cr(P3S9)2)] (EMIM=1-ethyl-3-methylimidazolium)
    Alexander, Grant C. B.
    Guillot-Deudon, Catherine
    Cody, Jason A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [3] Ionothermal synthesis and crystal structure of a 2D metal organic framework: [emim]2[Cd2(btec)Br2] (emim=1-ethyl-3-methylimidazolium, btec=1,2,4,5-benzenetetracarboxylate)
    Xie, Zai-Lai
    Feng, Mei-Ling
    Li, Jian-Rong
    Huang, Xiao-Ying
    INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (10) : 1143 - 1146
  • [4] Coordination environment around the lithium cation in solid Li2(EMIm)(N(SO2CF3)2)3 (EMIm=1-ethyl-3-methylimidazolium):: Structural clue of ionic liquid electrolytes for lithium batteries
    Matsumoto, Kazuhiko
    Hagiwara, Rika
    Tamada, Osamu
    SOLID STATE SCIENCES, 2006, 8 (09) : 1103 - 1107
  • [5] Electrodeposition of Copper Metal from the 1-Ethyl-3-methylimidazolium Fluoride ([EMIM]F)-urea-H2O System Containing Cu2O
    He, Wencai
    Shi, Zhongning
    Liu, Fengguo
    Yang, Shan
    ELECTROCHEMISTRY, 2020, 88 (04) : 253 - 255
  • [6] Structural Investigations and Thermal Behavior of (EMIm)[Cr(C2O4)2]•2H2O [1-Ethyl-3-methylimidazolium Chromium(III) Dioxalate Dihydrate]
    Kahlenberg, Volker
    Wertl, Waltraud
    Toebbens, Daniel M.
    Schottenberger, Herwig
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (10): : 1371 - 1377
  • [7] Synthesis and crystal structure of alkali metal oxo nitrido dimetallates(VI), A6[M2N4O3] (A ≡ K, Rb, Cs; M ≡ Mo, W)
    Niewa, R.
    Jacobs, H.
    1600, Elsevier Science S.A., Lausanne, Switzerland (217):
  • [8] SYNTHESIS AND CRYSTAL-STRUCTURE OF ALKALI-METAL OXO NITRIDO DIMETALLATES(VI), A(6)[M(2)N(4)O(3)] (A=K, RB, CS, M=MO, W)
    NIEWA, R
    JACOBS, H
    JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 217 (01) : 38 - 43
  • [9] Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)] n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n=1, 2, and 3)
    Pei, Huan
    Zhang, Luyong
    Cheng, Huanhuan
    Wang, Shibin
    Yang, Zhihua
    Zhang, Fangfang
    Pan, Shilie
    CHEMISTRY OF MATERIALS, 2024, 36 (23) : 11697 - 11705
  • [10] Synthesis and structural characterization of (C14H16N2)3(C14H17N2)2[β-Mo8O26]
    IKRAM ZEBIRI
    SIHEM BOUFAS
    SALIMA MOSBAH
    LEÏLA BENCHARIF
    MUSTAPHA BENCHARIF
    Journal of Chemical Sciences, 2015, 127 : 1769 - 1775
12345