Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages

被引：52
|
作者：
Xia, HP
Wen, TB
Hu, QY
Wang, X
Chen, XG
Shek, LY
Williams, ID
Wong, KS
Wong, GKL
Jia, GC
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[2] Hong Kong Univ Sci & Technol, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Kowloon, Hong Kong, Peoples R China
[3] Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Hong Kong, Peoples R China
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 04期
关键词：
D O I：
10.1021/om0496939
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of RuHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3, which reacts with PMe3 to give 1,3,5-[Cl(CO)(PMe3)(3)RuCH=CH](3)C6H3. 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)(2)RuCH=CH](3)C6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh3)(3) with ArCdropCH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3)(3). Reaction of OsHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HCdropC-3,5-[Cl(CO)(PPh3)(3)OsCH=CH](2)C6H3, which reacts with PMe3 to give 1-HCdropC-3,5-[OsCl(CO)(PPh3)(2)(PMe3)OsCH=CH](2)C6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.
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收藏
页码：562 / 569
页数：8
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