A soluble coordination polymer and its sol-gel-derived amorphous films: synthesis and third-order nonlinear optical properties

被引：19
|
作者：
Jiang, Peng [1 ]
Huang, Weimin [1 ]
Li, Jiangtian [1 ]
Zhuang, Dakui [1 ]
Shi, Jianlin [1 ]
机构：
[1] Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2008年 / 18卷 / 31期
关键词：
D O I：
10.1039/b807358a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new soluble tris(8-hydroxyquinoline) aluminium (AlQ(3))-based coordination polymer named CP-B8QBA-Al has been synthesized. In contrast with the traditional coordination polymers, this new coordination polymer CP-B8QBA-Al does not crystallize and can be fabricated into amorphous films by conventional spin- coating. The third-order nonlinear optical properties of the CP-B8QBA-Al films were investigated using the Z-scan method at 800 nm and 1064 nm, the results show the coordination polymer films have a third-order NLO susceptibility chi((3)) value as high as 1.66 X 10(-10) esu without nonlinear absorption.
引用
收藏
页码：3688 / 3693
页数：6
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