Catalytic Hydrocarboxylation of Alkenes and Alkynes with CO2

被引：107
|
作者：
Zhang, Yugen [1 ]
Riduan, Siti Nurhanna [1 ]
机构：
[1] Inst Bioengn & Nanotechnol, Singapore 138669, Singapore
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 28期
关键词：
carbon dioxide; homogeneous catalysis; hydrocarboxylation; synthetic methods; transition metals; CARBENE COPPER(I) COMPLEXES; C-H BONDS; CARBON-DIOXIDE; DIRECT CARBOXYLATION; BIS-1,3-DIENES; CYCLOADDITION; DERIVATIVES; CYCLIZATION; EPOXIDES; REAGENTS;
D O I：
10.1002/anie.201101341
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Taming the enemy: Great possibilities for the use of carbon dioxide as a renewable and environmentally friendly source of carbon in organic synthesis have been demonstrated through the hydrocarboxylation of simple alkenes and alkynes with CO2 (see scheme). Several versatile methods for carboxylic acid synthesis have been developed on this basis. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6210 / 6212
页数：3
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