Unexpected formation of aryl dialkyl carbinol as a side product from the reaction of methoxyarylaldehydes with Grignard reagents

被引：6

作者：

Sharma, A ^{[1
]}

Joshi, BP ^{[1
]}

Singh, NP ^{[1
]}

Sinha, AK ^{[1
]}

机构：

[1] Inst Himalayan Bioresource Technol, Nat Plant Prod Div, Palampur 176061, Himachal Prades, India

来源：

TETRAHEDRON | 2006年 / 62卷 / 05期

关键词：

aryl dialkyl carbinol; aryl alkyl carbinol; arylaldehyde; grignard reaction;

D O I：

10.1016/j.tet.2005.10.051

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the attempted formation of secondary aryl alkyl carbinols from the reaction of methoxyarylaldehydes with Grignard reagents, aryl dialkyl carbinols were formed as unexpected side products. A mechanism for their formation is proposed. (c) 2005 Published by Elsevier Ltd.

引用

页码：847 / 851

页数：5

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