Photochemically Driven Addition of Iminyl Radicals to Alkynyl Fischer Carbene Complexes

被引：10

作者：

Blanco-Lomas, Marina ^{[1
]}

Caballero, Alegria ^{[1
]}

Campos, Pedro J. ^{[1
]}

Gonzalez, Hector F. ^{[1
]}

Lopez-Sola, Susana ^{[1
]}

Rivado-Casas, Laura ^{[1
]}

Rodriguez, Miguel A. ^{[1
]}

Sampedro, Diego ^{[1
]}

机构：

[1] Univ La Rioja, Dept Quim, Grp Sintesis Quim Rioja, Unidad Asociada CSIC, E-26006 Logrono, Spain

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 13期

关键词：

INSERTION REACTION; CHEMISTRY; INVENTION;

D O I：

10.1021/om200438y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nitrogen-centered radicals, generated by the action of UV light, are capable of reacting with alkynyl Fischer carbene complexes in two ways, 1,2- and 1,4-addition. Our results constitute the first reported example of a photochemically driven reaction of this kind.

引用

页码：3677 / 3682

页数：6

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