Palladium-Catalyzed Dehydrogenative Coupling Reaction of Terminal Alkynes with Unactivated Alkenes

被引：6
|
作者：
Yada, Akira [1 ]
Nishi, Shoki [2 ]
Sato, Yuta [2 ]
Ichinoseki, Sakina [1 ]
Murakami, Masahiro [2 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Interdisciplinary Res Ctr Catalyt Chem, 1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan
[2] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan
来源：
JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2018年 / 65卷 / 01期
关键词：
Dehydrogenative coupling; Palladium; 1,3-Enyne; Terminal alkyne; Alkene; ACCESS; ALKYNYLATION; DERIVATIVES; 1,3-ENYNES; EPOXIDES; ENYNES;
D O I：
10.1002/jccs.201700268
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Terminal alkynes having a bulky substituent dehydrogenatively couple with unactivated terminal alkenes with catalysis of palladium. The terminal sp carbon forms a bond with the internal sp(2) carbon of the alkene regioselectively to produce branched, conjugated 1,3-enynes with wide functional group tolerance.
引用
收藏
页码：117 / 121
页数：5
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