Process for Treating Spent Liquor of the TMP Process with Biomass-Based Fly Ash

The spent liquor (SL) of the thermomechanical pulping (TMP) process has a high effluent load. In this work, biomass-based fly ash was used for adsorbing lignin of SL and thus for reducing the COD and turbidity of SL prior to sending SL to a wastewater treatment system. By treating SL with fly ash in a one-stage adsorption process under the conditions of a fly ash/SL ratio of 55 mg/g and 3 h at 30 degrees C, 67 mg/g of lignin was adsorbed on fly ash at room, temperature. Adjusting the pH of SL. had an insignificant influence on the lignin isolation from the system but affected the turbidity of SL. The lignin removal was 68% in a two-stage fly ash adsorption process, while the COD and turbidity removal were 70% and 94%, respectively. On the basis of the results, a process for reducing the effluent load of SL using fly ash was proposed.