Visible-Light-Initiated Cross-Dehydrogenative Coupling of Quinoxalin-2(1H)-ones and Simple Amides with Air as an Oxidant

被引：81

作者：

Xie, Long -Yong ^{[1
]}

Hu, Jia-Li ^{[1
]}

Song, Yan-Xi ^{[1
]}

Jia, Guo-Kai ^{[1
]}

Lin, Ying-Wu ^{[3
]}

He, Jun-Yi ^{[2
]}

Cao, Zhong ^{[2
]}

He, Wei-Min ^{[1
]}

机构：

[1] Hunan Univ Sci & Engn, Dept Chem, Yangzi Tang Rd 130, Yongzhou 425100, Peoples R China

[2] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Wanjiali Rd 960, Changsha 410114, Hunan, Peoples R China

[3] Univ South China, Sch Chem & Chem Engn, Changshen Rd 28, Hengyang 421001, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2019年 / 7卷 / 24期

关键词：

quinoxalin-2(1H)-ones; amidation; visible-light catalysis; ambient air; metal free; ARYLATION; QUINOXALIN-2(H)-ONES; TRIFLUOROMETHYLATION; PHOSPHONATION; CYCLIZATION; PHOTOREDOX; ALKYLATION; AMINATION; SALTS;

D O I：

10.1021/acssuschemeng.9b05715

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By using ambient air as an oxidant, various N-acylated 3-aminoquinoxalin-2(1H)-ones were efficiently synthesized through visible-light-promoted rhodamine B-catalyzed amidation reaction of quinoxalin-2(1H)-ones and amides under metal-free and strong oxidant-free conditions.

引用

页码：19993 / +

页数：13

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