A theoretical study on the nonlinear optical second-order properties of azobenzene series molecules

被引：0
|
作者：
Feng, JK
Wang, HC
Xiao, CY
Sun, CC
机构：
[1] ACAD SINICA, CHANGCHUN INST APPL CHEM, CHANGCHUN 130022, PEOPLES R CHINA
[2] JILIN UNIV, INST THEORET CHEM, CHANGCHUN 130023, PEOPLES R CHINA
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1996年 / 17卷 / 04期
关键词：
azo dyes; NLO second-order property; molecular design;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the basis of AM1 and INDO/CI methods, we devise the program for the calculation of nonlinear second-order optical susceptibilities beta(ijk) and perform systematic theoretical studies on the nonlinear optical second-order properties of azobenzene series molecules, i. e. on the basis of [GRAPHICS] we induced different donors on the left side of phenyl ring, and different accepters on the right side of phenyl ring, and examined the rule of beta variation. The regularity summarized from the calculated results has been explained micromechanically. Finally, a molecule having a big nonlinear second-order optical susceptibility has been designed.
引用
收藏
页码：596 / 600
页数：5
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