New Synthesis of Pine Sawfly Pheromones

被引：0

作者：

He, Guo-Guo ^{[1
]}

Yang, Xuan ^{[2
]}

Cheng, Yu ^{[2
]}

Bai, Hong-Jin ^{[1
]}

Zhang, Tao ^{[2
]}

Du, Zhen-Ting ^{[2
,3
]}

机构：

[1] Tarim Univ, Engn Lab Chem Resources Utilizat South Xinjiang, Xinjiang Prod & Construct Corps, Alar 843300, Peoples R China

[2] Northwest A&F Univ, Coll Chem & Pharm, Yangling 712100, Shaanxi, Peoples R China

[3] Key Lab Bot Pesticide R&D Shaanxi Prov, Yangling 712100, Shaanxi, Peoples R China

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 58卷 / 09期

关键词：

pine sawfly pheromones; stereocenters; (2S; 3S; 7S)-3; 7-dimethylpentadecan-2-ol; SEX-PHEROMONE; 3,7-DIMETHYLPENTADEC-2-YL ACETATE; ASYMMETRIC-SYNTHESIS; NEODIPRION-SERTIFER; ATTRACTANTS; COMPONENTS;

D O I：

10.1134/S1070428022090172

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Based on the previously synthesized chiral intermediate, a new synthesis of pine sawfly pheromones bearing 3 stereocenters has been achieved. The key steps were Evans' template induction, Wittig olefina-tion, and conventional chemical operations. (2S,3S,7S)-3,7-Dimethylpentadecan-2-yl acetate and propanoate were obtained in 9 steps with an overall yield of 34%.

引用

页码：1311 / 1318

页数：8

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