Synthesis and characterization of tungsten carbide fine powders

被引：36

作者：

Lukovic, Jelena ^{[1
]}

Babic, Biljana ^{[1
]}

Bucevac, Dusan ^{[1
]}

Prekajski, Marija ^{[1
]}

Pantic, Jelena ^{[1
]}

Bascarevic, Zvezdana ^{[2
]}

Matovic, Branko ^{[1
]}

机构：

[1] Univ Belgrade, Vinca Inst Nucl Sci, Belgrade 11001, Serbia

[2] Univ Belgrade, Inst Multidisciplinary Res, Belgrade 11030, Serbia

来源：

CERAMICS INTERNATIONAL | 2015年 / 41卷 / 01期

关键词：

WC powder; X-ray diffraction; Scanning electron microscopy; BET method; CATALYST SUPPORT; SURFACE-AREA; CARBON; ADSORPTION; BEHAVIOR; WC;

D O I：

10.1016/j.ceramint.2014.09.057

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Fine tungsten carbide (WC) powder was prepared by solid state reaction between tungsten powder (W) and activated carbon cloth as a new carbon (C) source. The effect of temperature and time of heat treatment as well as the effect of C/W ratio on WC phase formation was studied. The results obtained by X-ray powder diffraction (XRPD) show that obtained powder is single WC. Microstructure and morphology was determinate by means of scanning electron microscopy (SEM). Brunauer-Emmett-Teller (BET) method was used for examining specific surface area and texture of obtained powders. It was found that WC powder was successfully synthesized in excess carbon after eight-hour heat treatment at relatively low temperature (1000 degrees C). (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

引用

页码：1271 / 1277

页数：7

共 25 条

[1] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS
BARRETT, EP
JOYNER, LG
HALENDA, PP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) : 373 - 380
[2] ELECTRONIC-STRUCTURE AND CATALYTIC BEHAVIOR OF TUNGSTEN CARBIDE
BENNETT, LH
CUTHILL, JR
MCALISTER, AJ
ERICKSON, NE
WATSON, RE
[J]. SCIENCE, 1974, 184 (4136) : 563 - 565
[3] Borovinskaya I., 2012, Tungsten Carbide - Processing and Applications, P1
[4] Borovinskaya I. P., 2004, IAN SSSR NEORG MATER, V40, P1190
[5] Synthesis of crystalline metal nitride and metal carbide nanostructures by sol-gel chemistry
Giordano, Cristina
Antonietti, Markus
[J]. NANO TODAY, 2011, 6 (04) : 366 - 380
[6] Hugh O., 1996, Handbook of Refractory Carbides and Nitrides
[7] Synthesis of WC nanopowders from novel precursors
Jin, Yongzhong
Liu, Dongliang
Li, Xinyue
Yang, Ruisong
[J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2011, 29 (03) : 372 - 375
[8] Simple synthesis of graphitic porous carbon by hydrothermal method for use as a catalyst support in methanol electro-oxidation
Joo, Ji Bong
Kim, You Jung
Kim, Wooyoung
Kim, Pil
Yi, Jongheop
[J]. CATALYSIS COMMUNICATIONS, 2008, 10 (03) : 267 - 271
[9] Characterization of porous carbons with high resolution αs-analysis and low temperature magnetic susceptibility
Kaneko, K
Ishii, C
Kanoh, H
Hanzawa, Y
Setoyama, N
Suzuki, T
[J]. ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1998, 76 : 295 - 320
[10] Synthesis of WC and dense WC-xvol.%Co hard materials by high-frequency induction heated combustion method
Kim, HC
Oh, DY
Shon, IJ
[J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2004, 22 (01) : 41 - 49

← 1 2 3 →