Silica triflate as a new, mild and efficient catalyst for tetra hydropyranylation of alcohols and deprotection of tetra hydropyranyl ethers

被引:4
|
作者
Shirini, F. [1 ]
Marjani, K.
Nahzomi, H. Taherpour
机构
[1] Guilan Univ, Coll Sci, Dept Chem, Rasht, Iran
[2] Teacher Training Univ, Fac Chem, Tehran, Iran
关键词
alcohols; silica gel; silica triflate; tetrahydropyranylation; trifluoromethanesulfonyl chloride;
D O I
10.1080/10426500701407839
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Silica triflate, a new stable derivative of silica gel, is easily prepared by the reaction of silica gel with trifluoromethanesulfonyl chloride. Silica triflate acts as a highly effective and reusable catalyst for tetrahydropyranylation of alcohols and deprotection of tetrahydropyranyl ethers under mild and completely heterogeneous reaction conditions.
引用
收藏
页码:2235 / 2240
页数:6
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