Immobilized ruthenium complexes bearing N,O-bidentate ligands

被引：0

作者：

Dragutan, Valerian ^{[1
]}

Verpoort, Francis ^{[2
]}

机构：

[1] Roumanian Acad, Inst Organ Chem CD Nenitescu, Bucharest 060023, Romania

[2] Univ Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium

来源：

REVUE ROUMAINE DE CHIMIE | 2007年 / 52卷 / 8-9期

关键词：

N; O-bidentate ligands; immobilized Ru complexes; Schiff-base; ring-closing metathesis; Kharasch addition; enol-ester; atom transfer radical polymerization;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Immobilization of a family of arene and benzylidene N,O-bidentate ruthenium complexes by covalently anchoring the homogeneous complexes on MCM-41 is described. Successful applications of these immobilized catalytic systems in enol-ester synthesis, Kharasch addition, ring-closing metathesis (RCM), ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) are illustrated. Important advantages of these heterogeneous catalyst systems in comparison with their homogeneous counterparts are also highlighted.

引用

页码：905 / +

页数：12

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