Crystal structure and magnetic properties of polybis(formamide)bis(μ-formato)cobalt(II):: An extended two-dimensional square lattice material which exhibits spontaneous magnetization below 9 K

被引：123
|
作者：
Rettig, SJ [1 ]
Thompson, RC [1 ]
Trotter, J [1 ]
Xia, SH [1 ]
机构：
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
来源：
INORGANIC CHEMISTRY | 1999年 / 38卷 / 06期
关键词：
D O I：
10.1021/ic980742h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the title compound extended sheets of cobalt(II) ions, linked in a square array by bridging formates, couple antiferromagnetically. Spin canting generates residual spin on the sheets, and interaction between the sheets leads to long-range ferromagnetic ordering and spontaneous magnetization below 9 K.
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收藏
页码：1360 / +
页数：5
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