Characteristics of intrinsic non-stationarity and its effect on eddy-covariance measurements of CO2 fluxes

Stationarity is a critical assumption in the eddy-covariance method that is widely used to calculate turbulent fluxes. Many methods have been proposed to diagnose non-stationarity attributed to external non-turbulent flows. In this paper, we focus on intrinsic non-stationarity (IN) attributed to turbulence randomness. The detrended fluctuation analysis is used to quantify IN of CO(2 )turbulent fluxes in the downtown of Beijing. Results show that the IN is common in CO2 turbulent fluxes and is a small-scale phenomenon related to the inertial sub-range turbulence. The small-scale IN of CO2 turbulent fluxes can be simulated by the Ornstein-Uhlenbeck (OU) process as a first approximation Based on the simulation results, we find that the flux-averaging time should be greater than 27 s to avoid the effects of IN. Besides, the non-stationarity diagnosis methods that do not take into account IN would possibly make a wrong diagnosis with some parameters.