Hydrogenolysis of benzofuran using aqueous ethanol solution over graphite-supported platinum catalyst

被引:0
|
作者
Hiraishi, Yushi [1 ]
Minakawa, Naohiro [1 ]
Taniguchi, Kenkichi [1 ]
Nagasawa, Yoshiyuki [1 ]
Nanao, Hidetaka [1 ]
Rode, Chandrashekhar, V [2 ]
Sato, Osamu [3 ]
Yamaguchi, Aritomo [3 ]
Shirai, Masayuki [1 ,3 ]
机构
[1] Iwate Univ, Fac Engn, Dept Chem & Bioengn, 4-3-5 Ueda, Morioka, Iwate 0208551, Japan
[2] CSIR Natl Chem Lab, Chem Engn & Proc Dev Div, Dr Homi Bhabha Rd, Pune 41108, Maharashtra, India
[3] Natl Inst Adv Ind Sci & Technol, Res Inst Chem Proc Technol, Miyagino Ku, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan
关键词
Graphite support; Platinum catalysts; Hydrogenolysis; Biomass conversion; SUPERCRITICAL WATER;
D O I
10.1016/j.jics.2021.100021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphite-supported platinum catalysts (Pt/G) were highly active for the hydrogenolysis of benzofuran to o-ethylphenol in aqueous ethanol solution at 523 K without using any external hydrogen gas. The hydrogenolysis activities and selectivity to o-ethylphenol in ethanol solution over Pt/G were higher than those with a conventional method using externally supplied hydrogen gas. Both water and ethanol were indispensable for the hydrogenolysis in aqueous ethanol solution at 523 K.
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页数:4
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