About Durability of Biodegradable Polymers: Structure/Degradability Relationships

被引:17
|
作者
Commereuc, S. [1 ,3 ]
Askanian, H. [2 ,3 ]
Verney, V. [2 ,3 ]
Celli, A. [4 ]
Marchese, P. [4 ]
机构
[1] Clermont Univ, ENSCCF, LPMM, BP 10448, F-63000 Clermont Ferrand, France
[2] Univ Blaise Pascal, Clermont Univ, LPMM, Clermont Ferrand F-63000, France
[3] CNRS, UMR 6505, LPMM, F-63174 Aubiere, France
[4] Dipartimento Chim, Appl Sci Mat, Bologna 40131, Italy
来源
关键词
biodegradable; copolymerization; degradation; polyesters; rheology; RHEOLOGICAL PROPERTIES; RANDOM COPOLYMERS; THERMAL-BEHAVIOR; MELTS;
D O I
10.1002/masy.201051052
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Up to now materials were chosen to satisfy specific property(ies) in relation with the required application. Nowadays, a specific attention has to be devoted to the durability of this property regarding to the lifetime duration. It is the reason why, we paid attention about degradability. Thus, a screening of bio- and photodegradability of various selected (co)polyesters has been achieved in order to get better insights about structure / durability relationships. We developed tools allowing the prediction of the behavior of materials upon ageing and the evolution of their properties, regarding to their initial chemical structures. Hence, we could be able to design (co)polyesters characterized by well-adapted physical, thermal and mechanical properties, but also, with high photostability and/or high biodegradability.
引用
收藏
页码:378 / +
页数:3
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