Emissions of polycyclic aromatic hydrocarbons from thermal pre-treatment of waste hydrodesulfurization catalysts

Despite increasing environmental concerns and stringent limitations on the sulfur content in fuels, many waste hydrodesulfurization (HDS) catalysts containing Co, Mo, Ni and V are generated in the petroleum refining process. To recover valuable metals in the waste HDS catalysts via hydrometallurgy, thermal treatment is usually performed first to remove contaminants (residual oil, carbon and sulfur) present on the surface of catalysts. In this study, the mass partitions of polycyclic aromatic hydrocarbons (PAHs) in different media (aqueous, particulate and gaseous) were quantified in order to determine the efficiency of three different air pollution control devices, cooling unit, filter and glass cartridge, on PAH removal. An afterburner and two furnace temperatures were used to observe the effect on the PAH contents of the treated residues. Results show that total-PAH content in treated residues decreased with the pyrolysis temperature of the primary furnace, while those generated in flue gases were destroyed by the afterburner at an efficiency of approximately 95%. In addition, the thermal process converts high molecular weight PAHs to low molecular weight PAHs, and the afterburner temperature involved (1200 degrees C) was high enough to prohibit the generation of high molecular weight PAHs (HM-PAHs), leading to the domination of low molecular weight PAHs (LM-PAHs) in flue gases, while treated residues were dominated by HM-PAHs. Finally, information on metal contents and their concentrations in the Toxicity Characteristic Leaching Procedure in waste HDS catalyst and thermal treated residues are examined as an index of the potential for metal recovery. (c) 2007 Elsevier Ltd. All rights reserved.