Crystal and Molecular Structure of Palladium(II) and Silver(I) Complexes with Oxotetrazolinate Ligands [1-Me-N4C(O)]-

被引:2
|
作者
Noeth, Heinrich [1 ]
Burger, Klaus [1 ]
Beck, Wolfgang [1 ]
机构
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
关键词
Oxotetrazolinate; Palladium; Silver; Phosphines; X-Ray Crystallography; TRANSITION-METAL-COMPLEXES; PD(II) AZIDO COMPLEXES; CYCLOADDITION REACTIONS; TRIMETHYLSILYL AZIDE; ORGANIC ISOCYANIDES; COORDINATED AZIDE; ISOTHIOCYANATES; DERIVATIVES; NICKEL(II); REACTIVITY;
D O I
10.1515/znb-2011-0917
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The structures of (n-Bu3P)(2)Pd[1-Me-N4C(O)](2) (1) and of (Ph3P)(3)Ag[1-Me-N4C(O)]center dot 1-Me-4-H-N4C(O) (2) were determined by X-ray crystallography. The oxotetrazolinate hgands are N-4-coordinated in contrast to the corresponding S-coordinated tetrazole-thionates.
引用
收藏
页码:972 / 974
页数:3
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