Complexes of Pd(II) and Zn(II) chlorides with anthracene-containing α-amino oxime derived from the naturally occurring monoterpenoid (+)-3-carene

被引：5
|
作者：
Larionov, S. V. [1 ,2 ]
Kokina, T. E. [1 ,2 ]
Myachina, L. I. [1 ]
Glinskaya, L. A. [1 ]
Rakhmanova, M. I. [1 ]
Naumov, D. Yu. [1 ]
Tkachev, A. V. [2 ,3 ]
Agafontsev, A. M. [2 ,3 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 41卷 / 03期
关键词：
EU(III) COMPLEXES; CRYSTAL-STRUCTURE; PYRAZOLYLQUINOLINE; PHOTOLUMINESCENCE; SENSORS;
D O I：
10.1134/S1070328415030070
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex Pd(HL)Cl-2 (I) was obtained (HL is the anthracene-containing chiral alpha-amino oxime derived from the natural monoterpenoid (+)-3-carene). Single crystals of its solvate [Pd(HL)Cl-2] center dot 0.33EtOH (II) were grown. According to X-ray diffraction data (CIF file CCDC no. 1008947), the crystals are built from mononuclear molecules of complex I and uncoordinated EtOH molecules. The coordination environment of the Pd atom in complex I (PdCl2N2) makes up a distorted square (trapezoid). The compound HL acts as a chelating bidentate ligand. The [Pd(HL)Cl-2] and EtOH molecules are united into chains through weak hydrogen bonds. The photoluminescence (PL) of HL and the system ZnCl2-HL in acetonitrile was studied. The emission spectra show three bands at 394, 415, and 440 nm. The photoluminescence of the system ZnCl2-HL in solution is more intense than that of HL. A study of the system ZnCl2-HL by the molar ratio method in conjunction with emission spectroscopy suggests the formation of the complex Zn(HL)Cl-2 in acetonitrile.
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收藏
页码：162 / 168
页数：7
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