The ''Thio-Arbuzov'' reaction of sulfenate esters with sulfenyl chlorides: Fate of the thiosulfinate product.

被引:13
|
作者
Brown, C
Evans, GR
机构
[1] Chemical Laboratory, University of Kent at Canterbury, Canterbury, Kent
[2] SmithKline Beecham Pharmaceuticals, The Frythe, Welwyn, Hertfordshire
[3] Chiroscience, Cambridge, CB4 4WE, Cambridge Science Park, Milton Rd
关键词
D O I
10.1016/S0040-4039(96)02096-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The further reaction of thiosulfinate esters (putative products of the ''Thio-Arbuzov'' reaction of sulfenate esters with sulfenyl chlorides) with sulfenyl chlorides and sulfenate esters has been studied. In the former case, sulfinyl chlorides and disulfides are formed. In the latter case sulfinate esters and disulfides are obtained. Copyright (C) 1996 Elsevier Science Ltd
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页码:9101 / 9104
页数:4
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