Ion-selective electrode for determining thallium(III) as its complexonate

被引:4
|
作者
Kharitonov, SV [1 ]
Zarembo, VI [1 ]
机构
[1] Tech Univ, St Petersburg State Technol Inst, St Petersburg 190013, Russia
关键词
D O I
10.1007/s10809-005-0238-z
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The main electroanalytical characteristics of film membrane ion-selective electrodes (ISEs) based on high-molecular-weight quaternary ammonium salts (QASs) are studied. These electrodes are reversible to a complex of thallium(III) with N,N'-dioctylethylenediamine-N,N'-disuccinic acid. It is found that the selectivity of the ISEs to the potential-determining ion depends on the structure of the QAS. A procedure for the synthesis of N,N'-dioctylethylenediamine-N,N'-disuccinic acid is described.
引用
收藏
页码:1056 / 1061
页数:6
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