Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides

被引：9
|
作者：
Shavrin, Konstantin N. [1 ]
Gvozdev, Valentin D. [1 ]
Yurov, Serafim V. [2 ]
Nefedov, Oleg M. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[2] DI Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia
来源：
MENDELEEV COMMUNICATIONS | 2008年 / 18卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1016/j.mencom.2008.01.007
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Depending on the substituent at the triple bond, the reaction of 1-(alk-1-ynyl)-1-chlorocyclopropanes 1 with lithium monoalkylamides in THF gives hitherto unknown conjugated iminocyclopropenes 2 or 4-substituted 1,1-dimethylbuta-1,2-dienes 3 in up to 60% yields.
引用
收藏
页码：16 / 17
页数：2
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