Formation of macromolecular metal-complexes in aqueous solutions of carboxyl-containing copolymers. The role of intramolecular interactions

被引：0
|
作者：
Anufrieva, EV [1 ]
Krakovyak, MG [1 ]
Anan'eva, TD [1 ]
Gromova, RA [1 ]
Lushchik, VB [1 ]
Nekrasova, TN [1 ]
机构：
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
来源：
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1998年 / 40卷 / 11期
关键词：
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The composition and stability of macromolecular metal-complexes formed by different carboxyl-containing copolymers and the ions of polyvalent metals (Fe3+, Al3+) were determined. The amount of Fe3+ ions bound with copolymer was estimated by a variation in the absorption spectra of aqueous solutions. The stability of the copolymer-metal ion complexes was studied by the luminescence quenching of a polymer solution labeled with luminescent ions, the process being related to the lifetime of these ions in the complexes with macromolecules.
引用
收藏
页码：1847 / 1853
页数：7
相关论文
共 17 条
12