The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them

被引:9
|
作者
Dey, Sandeep Kumar [1 ]
Janiak, Christoph [2 ]
机构
[1] Goa Univ, Sch Chem Sci, Taleigao Plateau 403206, Goa, India
[2] Heinrich Heine Univ Dusseldorf, Inst Inorgan & Struct Chem, D-40225 Dusseldorf, Germany
关键词
RECEPTOR CHEMISTRY HIGHLIGHTS; NAKED-EYE DETECTION; SCHIFF-BASE; ATMOSPHERIC CO2; ANION RECOGNITION; FIXATION; UREA; CARBONATE; CAPSULES; CYANIDE;
D O I
10.1039/d0ra02293d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluoride-ion induced hydrolysis of imine (C=N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene compounds (SL and CL1-3) based on H-1-NMR, F-19-NMR, LC-MS and UV-vis spectroscopy experiments.
引用
收藏
页码:14689 / 14693
页数:5
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